Physical Chemistry 2nd Edition Ball Solutions Manual

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Product Details:

  • ISBN-10 ‏ : ‎ 1133958435
  • ISBN-13 ‏ : ‎ 978-1133958437
  • Author: Ball

With its easy-to-read approach and focus on core topics, PHYSICAL CHEMISTRY, 2e provides a concise, yet thorough examination of calculus-based physical chemistry. The Second Edition, designed as a learning tool for students who want to learn physical chemistry in a functional and relevant way, follows a traditional organization and now features an increased focus on thermochemistry, as well as new problems, new two-column examples, and a dynamic new four-color design. Written by a dedicated chemical educator and researcher, the text also includes a review of calculus applications as applied to physical chemistry.

 

Table of Content:

  1. Ch 1: Gases and the Zeroth Law of Thermodynamics
  2. Introduction
  3. 1.1: Synopsis
  4. 1.2: System, Surroundings, and State
  5. 1.3: The Zeroth Law of Thermodynamics
  6. 1.4: Equations of State
  7. 1.5: Partial Derivatives and Gas Laws
  8. 1.6: Nonideal Gases
  9. 1.7: More on Derivatives
  10. 1.8: A Few Partial Derivatives Defined
  11. 1.9: Thermodynamics at the Molecular Level
  12. 1.10: Summary
  13. Key Equations
  14. Exercises for Chapter 1
  15. Ch 2: The First Law of Thermodynamics
  16. Introduction
  17. 2.1: Synopsis
  18. 2.2: Work and Heat
  19. 2.3: Internal Energy and the First Law of Thermodynamics
  20. 2.4: State Functions
  21. 2.5: Enthalpy
  22. 2.6: Changes in State Functions
  23. 2.7: Joule-Thomson Coefficients
  24. 2.8: More on Heat Capacities
  25. 2.9: Phase Changes
  26. 2.10: Chemical Changes
  27. 2.11: Changing Temperatures
  28. 2.12: Biochemical Reactions
  29. 2.13: Summary
  30. Key Equations
  31. Exercises for Chapter 2
  32. Ch 3: The Second and Third Laws of Thermodynamics
  33. Introduction
  34. 3.1: Synopsis
  35. 3.2: Limits of the First Law
  36. 3.3: The Carnot Cycle and Efficiency
  37. 3.4: Entropy and the Second Law of Thermodynamics
  38. 3.5: More on Entropy
  39. 3.6: Order and the Third Law of Thermodynamics
  40. 3.7: Entropies of Chemical Reactions
  41. 3.8: Summary
  42. Key Equations
  43. Exercises for Chapter 3
  44. Ch 4: Gibbs Energy and Chemical Potential
  45. Introduction
  46. 4.1: Synopsis
  47. 4.2: Spontaneity Conditions
  48. 4.3: The Gibbs Energy and the Helmholtz Energy
  49. 4.4: Natural Variable Equations and Partial Derivatives
  50. 4.5: The Maxwell Relationships
  51. 4.6: Using Maxwell Relationships
  52. 4.7: Focus on ∆G
  53. 4.8: The Chemical Potential and Other Partial Molar Quantities
  54. 4.9: Fugacity
  55. 4.10: Summary
  56. Key Equations
  57. Exercises for Chapter 4
  58. Ch 5: Introduction to Chemical Equilibrium
  59. Introduction
  60. 5.1: Synopsis
  61. 5.2: Equilibrium
  62. 5.3: Chemical Equilibrium
  63. 5.4: Solutions and Condensed Phases
  64. 5.5: Changes in Equilibrium Constants
  65. 5.6: Amino Acid Equilibria
  66. 5.7: Summary
  67. Key Equations
  68. Exercises for Chapter 5
  69. Ch 6: Equilibria in Single-Component Systems
  70. Introduction
  71. 6.1: Synopsis
  72. 6.2: A Single-Component System
  73. 6.3: Phase Transitions
  74. 6.4: The Clapeyron Equation
  75. 6.5: Gas-Phase Effects
  76. 6.6: Phase Diagrams and the Phase Rule
  77. 6.7: Natural Variables and Chemical Potential
  78. 6.8: Summary
  79. Key Equations
  80. Exercises for Chapter 6
  81. Ch 7: Equilibria in Multiple-Component Systems
  82. Introduction
  83. 7.1: Synopsis
  84. 7.2: The Gibbs Phase Rule
  85. 7.3: Two Components: Liquid/Liquid Systems
  86. 7.4: Nonideal Two-Component Liquid Solutions
  87. 7.5: Liquid/Gas Systems and Henry’s Law
  88. 7.6: Liquid/Solid Solutions
  89. 7.7: Solid/Solid Solutions
  90. 7.8: Colligative Properties
  91. 7.9: Summary
  92. Key Equations
  93. Exercises for Chapter 7
  94. Ch 8: Electrochemistry and Ionic Solutions
  95. Introduction
  96. 8.1: Synopsis
  97. 8.2: Charges
  98. 8.3: Energy and Work
  99. 8.4: Standard Potentials
  100. 8.5: Nonstandard Potentials and Equilibrium Constants
  101. 8.6: Ions in Solution
  102. 8.7: Debye-Hückel Theory of Ionic Solutions
  103. 8.8: Ionic Transport and Conductance
  104. 8.9: Summary
  105. Key Equations
  106. Exercises for Chapter 8
  107. Ch 9: Pre-Quantum Mechanics
  108. Introduction
  109. 9.1: Synopsis
  110. 9.2: Laws of Motion
  111. 9.3: Unexplainable Phenomena
  112. 9.4: Atomic Spectra
  113. 9.5: Atomic Structure
  114. 9.6: The Photoelectric Effect
  115. 9.7: The Nature of Light
  116. 9.8: Quantum Theory
  117. 9.9: Bohr’s Theory of the Hydrogen Atom
  118. 9.10: The de Broglie Equation
  119. 9.11: The End of Classical Mechanics
  120. Key Equations
  121. Exercises for Chapter 9
  122. Ch 10: Introduction to Quantum Mechanics
  123. Introduction
  124. 10.1 Synopsis
  125. 10.2 The Wavefunction
  126. 10.3: Observables and Operators
  127. 10.4: The Uncertainty Principle
  128. 10.5: The Born Interpretation of the Wavefunction; Probabilities
  129. 10.6: Normalization
  130. 10.7: The Schrödinger Equation
  131. 10.8: An Analytic Solution: The Particle-in-a-Box
  132. 10.9: Average Values and Other Properties
  133. 10.10: Tunneling
  134. 10.11: The Three-Dimensional Particle-in-a-Box
  135. 10.12: Degeneracy
  136. 10.13: Orthogonality
  137. 10.14: The Time-Dependent Schrödinger Equation
  138. 10.15: Summary of Postulates
  139. Key Equations
  140. Exercises for Chapter 10
  141. Ch 11: Quantum Mechanics: Model Systems and the Hydrogen Atom
  142. Introduction
  143. 11.1: Synopsis
  144. 11.2: The Classical Harmonic Oscillator
  145. 11.3: The Quantum-Mechanical Harmonic Oscillator
  146. 11.4: The Harmonic Oscillator Wavefunctions
  147. 11.5: The Reduced Mass
  148. 11.6: Two-Dimensional Rotations
  149. 11.7: Three-Dimensional Rotations
  150. 11.8: Other Observables in Rotating Systems
  151. 11.9: The Hydrogen Atom: A Central Force Problem
  152. 11.10: The Hydrogen Atom: The Quantum-Mechanical Solution
  153. 11.11: The Hydrogen Atom Wavefunctions
  154. 11.12: Summary
  155. Key Equations
  156. Exercises for Chapter 11
  157. Ch 12: Atoms and Molecules
  158. Introduction
  159. 12.1: Synopsis
  160. 12.2: Spin
  161. 12.3: The Helium Atom
  162. 12.4: Spin Orbitals and the Pauli Principle
  163. 12.5: Other Atoms and the Aufbau Principle
  164. 12.6: Perturbation Theory
  165. 12.7: Variation Theory
  166. 12.8: Linear Variation Theory
  167. 12.9: Comparison of Variation and Perturbation Theories
  168. 12.10: Simple Molecules and the Born-Oppenheimer Approximation
  169. 12.11: Introduction to LCAO-MO Theory
  170. 12.12: Properties of Molecular Orbitals
  171. 12.13: Molecular Orbitals of Other Diatomic Molecules
  172. 12.14: Summary
  173. Key Equations
  174. Exercises for Chapter 12
  175. Ch 13: Introduction to Symmetry in Quantum Mechanics
  176. Introduction
  177. 13.1: Synopsis
  178. 13.2: Symmetry Operations and Point Groups
  179. 13.3: The Mathematical Basis of Groups
  180. 13.4: Molecules and Symmetry
  181. 13.5: Character Tables
  182. 13.6: Wavefunctions and Symmetry
  183. 13.7: The Great Orthogonality Theorem
  184. 13.8: Using Symmetry in Integrals
  185. 13.9: Symmetry-Adapted Linear Combinations
  186. 13.10: Valence Bond Theory
  187. 13.11: Hybrid Orbitals
  188. 13.12: Summary
  189. Key Equations
  190. Exercises for Chapter 13
  191. Ch 14: Rotational and Vibrational Spectroscopy
  192. Introduction
  193. 14.1: Synopsis
  194. 14.2: Selection Rules
  195. 14.3: The Electromagnetic Spectrum
  196. 14.4: Rotations in Molecules
  197. 14.5: Selection Rules for Rotational Spectroscopy
  198. 14.6: Rotational Spectroscopy
  199. 14.7: Centrifugal Distortions
  200. 14.8: Vibrations in Molecules
  201. 14.9: The Normal Modes of Vibration
  202. 14.10: Quantum-Mechanical Treatment of Vibrations
  203. 14.11: Selection Rules for Vibrational Spectroscopy
  204. 14.12: Vibrational Spectroscopy of Diatomic and Linear Molecules
  205. 14.13: Symmetry Considerations for Vibrations
  206. 14.14: Vibrational Spectroscopy of Nonlinear Molecules
  207. 14.15: Nonallowed and Nonfundamental Vibrational Transitions
  208. 14.16: Group Frequency Regions
  209. 14.17: Rotational-Vibrational Spectroscopy
  210. 14.18: Raman Spectroscopy
  211. 14.19: Summary
  212. Key Equations
  213. Exercises for Chapter 14
  214. Ch 15: Introduction to Electronic Spectroscopy and Structure
  215. Introduction
  216. 15.1: Synopsis
  217. 15.2: Selection Rules
  218. 15.3: The Hydrogen Atom
  219. 15.4: Angular Momenta: Orbital and Spin
  220. 15.5: Multiple Electrons: Term Symbols and Russell-Saunders Coupling
  221. 15.6: Electronic Spectra of Diatomic Molecules
  222. 15.7: Vibrational Structure and the Franck-Condon Principle
  223. 15.8: Electronic Spectra of Polyatomic Molecules
  224. 15.9: Electronic Spectra of π Electron Systems: Hückel Approximations
  225. 15.10: Benzene and Aromaticity
  226. 15.11: Fluorescence and Phosphorescence
  227. 15.12: Lasers
  228. 15.13: Summary
  229. Key Equations
  230. Exercises for Chapter 15
  231. Ch 16: Introduction to Magnetic Spectroscopy
  232. Introduction
  233. 16.1: Synopsis
  234. 16.2: Magnetic Fields, Magnetic Dipoles, and Electric Charges
  235. 16.3: Zeeman Spectroscopy
  236. 16.4: Electron Spin Resonance
  237. 16.5: Nuclear Magnetic Resonance
  238. 16.6: Summary
  239. Key Equations
  240. Exercises for Chapter 16
  241. Ch 17: Statistical Thermodynamics: Introduction
  242. Introduction
  243. 17.1: Synopsis
  244. 17.2: Some Statistics Necessities
  245. 17.3: The Ensemble
  246. 17.4: The Most Probable Distribution: Maxwell-Boltzmann Distribution
  247. 17.5: Thermodynamic Properties from Statistical Thermodynamics
  248. 17.6: The Partition Function: Monatomic Gases
  249. 17.7: State Functions in Terms of Partition Functions
  250. 17.8: Summary
  251. Key Equations
  252. Exercises for Chapter 17
  253. Ch 18: More Statistical Thermodynamics
  254. Introduction
  255. 18.1: Synopsis
  256. 18.2: Separating q: Nuclear and Electronic Partition Functions
  257. 18.3: Molecules: Electronic Partition Functions
  258. 18.4: Molecules: Vibrations
  259. 18.5: Diatomic Molecules: Rotations
  260. 18.6: Polyatomic Molecules: Rotations
  261. 18.7: The Partition Function of a System
  262. 18.8: Thermodynamic Properties of Molecules from Q
  263. 18.9: Equilibria
  264. 18.10: Crystals
  265. 18.11: Summary
  266. Key Equations
  267. Exercises for Chapter 18
  268. Ch 19: The Kinetic Theory of Gases
  269. Introduction
  270. 19.1: Synopsis
  271. 19.2: Postulates and Pressure
  272. 19.3: Definitions and Distributions of Velocities of Gas Particles
  273. 19.4: Collisions of Gas Particles
  274. 19.5: Effusion and Diffusion
  275. 19.6: Summary
  276. Key Equations
  277. Exercises for Chapter 19
  278. Ch 20: Kinetics
  279. Introduction
  280. 20.1: Synopsis
  281. 20.2: Rates and Rate Laws
  282. 20.3: Characteristics of Specific Initial Rate Laws
  283. 20.4: Equilibrium for a Simple Reaction
  284. 20.5: Parallel and Consecutive Reactions
  285. 20.6: Temperature Dependence
  286. 20.7: Mechanisms and Elementary Processes
  287. 20.8: The Steady-State Approximation
  288. 20.9: Chain and Oscillating Reactions
  289. 20.10: Transition-State Theory
  290. 20.11: Summary
  291. Key Equations
  292. Exercises for Chapter 20
  293. Ch 21: The Solid State: Crystals
  294. Introduction
  295. 21.1: Synopsis
  296. 21.2: Types of Solids
  297. 21.3: Crystals and Unit Cells
  298. 21.4: Densities
  299. 21.5: Determination of Crystal Structures
  300. 21.6: Miller Indices
  301. 21.7: Rationalizing Unit Cells
  302. 21.8: Lattice Energies of Ionic Crystals
  303. 21.9: Crystal Defects and Semiconductors
  304. 21.10: Summary
  305. Key Equations
  306. Exercises for Chapter 21
  307. Ch 22: Surfaces
  308. Introduction
  309. 22.1: Synopsis
  310. 22.2: Liquids: Surface Tension
  311. 22.3: Interface Effects
  312. 22.4: Surface Films
  313. 22.5: Solid Surfaces
  314. 22.6: Coverage and Catalysis
  315. 22.7: Summary
  316. Key Equations
  317. Exercises for Chapter 22
  318. Appendixes
  319. Appendix 1: Useful Integrals
  320. Appendix 2: Thermodynamic Properties of Various Substances
  321. Appendix 3: Character Tables
  322. Appendix 4: Infrared Correlation Tables
  323. Appendix 5: Nuclear Properties
  324. Answers to Selected Exercises
  325. Index

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